I've only just bought this book and had a glance through the whole thing. It's filled with lots of great quality photos both of the films and behind the scenes with some informative quotes from the crew including producers, directors, stuntmen and some other film makers who have been influenced by Bond such as Steven Spielberg and Peter Jackson. It's the sort of book you can pick up for 2 minutes rather than reading for the afternoon as the emphasis really is on the photos.
Casino Royale: Theres a fair amount of photos from the new film. Many of which have already been seen on the internet etc but there are a few new ones, mainly the first full shot of Bond being tortured. I'd think carefully if your only buying this book for Casino Royale info though as the upcoming Bond On Set book would be more down your street but it's great to compare it to the previous films.
My only complaint is that theres virtually nothing from any of the 80s Bond films. They just seem to have been ignored which is a shame really as the book has little on timothy Dalton or any of the later Moore films. Otherwise a great book let down by this one appalling oversight.