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This review is from: Engines of Creation: The Coming Era of Nanotechnology (Anchor Library of Science) (Paperback)
Drexler is the one that they all refer to when discussing nanotechnology. He discusses the concept in a way that I found easy to read, and makes the various points in a clear, concise manner. He actually raises a number of key questions within the text, concerning just how we will define this in the future and how these concepts will impact upon human society.
If this is a topic that you have an interest in, or you want to understand how this technology could change the world, then this is where you should start. It will lay the groundwork that will help you make sense of some of the other works out there.