Good place to start.,
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This review is from: HTML5 and CSS3: Develop with Tomorrow's Standards Today (Pragmatic Programmers) (Paperback)
If you have a history in HTML and CSS and are just looking for whats new and how to implement the new draft specifications this book is very good.
I am currently writing a dissertation and part of my research is new web technologies. So far I have referenced this book about 14 times.
Definitly recomend to anyone interested in keeping up with the times and doesn't want to spend hours reading websites on a glary PC screen.
Any questions for me just leave a comment, I'm happy to help give more detailed information if required.