This is an odd assortment, I wouldn't call it a best-of. Not everything's live; there are three cuts from Jonathan Goes Country... Four cuts are the original Modern Lovers, and, not having absolutely everything by JR right now, I'm not sure if all those cuts have been released elsewhere. But I think the cuts that might be unique to this CD are The Neighbors, Velvet Underground, The Girl Stands Up to Me Now, Fender Stratocaster, and That Summer Feeling. The run times are a bit different from the studio versions I have. And since this is such a slapped-together collection, I doubt that extra effort was put into finding unique, different versions.
Live versions by Jonathan are always somewhat different from their studio counterparts, so if you love that about him, you'll want to get this.
I gave this 4 stars because there's absolutely no info on the CD other than song titles and writing credits. And, as someone else hinted, there's not much thought given to which songs were chosen or how they were ordered on the CD. But, if you're just wanting a sampler of JR's 80s-90s stuff, it will do you well.