At least Domino are honest. This has been released to tie in with the tour, and I for one have no beef with my favourite band making a few bucks after the event. Hey, they even waited the 10 years promised, 'scool!
It's exactly what it says, an overview, and probably how the live set lists will look - I'd guess way too many crowd pleasers for the die-hard fans' liking and some real oddballs thrown in. A reviewer above moans at the lack of B-sides etc but we have Shoot the Singer from an EP (gorgeous) and Picket Fence, some freaky homage to REM from the No Alternative comp back in '92 or '93, heh. I think it has the right balance, the moods seem to flow well enough (I can hear this record without hearing it, ok!) and it ends on a freaky album track prog-out.
Of course, it's needless if you're a fan, and rather like the recent Radiohead Best-Of, they weren't a singles band so this is a little jarring for the long-termers. What it will do, hopefully, is lead to people spotting favourite tracks, finding that the albums have very clear personalities, and then going for one of the brilliant album re-releases, complete with all odds and ends from the same period.
As a final note, S&E's re-release ends with early Peel sessions and the Brixton '91 gig supporting Sonic Youth, and it's awesome. I'd say THAT's the Pavement that made people fall in love, a good insight to the early band and a logical progression from older, interesting and do-it-your-own-way bands like the Fall, Chrome (!), early Mary Chain, Zappa, and I think it's this that secures their place. Their contemporaries don't hold up in retrospect, and I don't think anyone's advanced further since.