Debugging Perl is an ideal introduction to writing robust code in Perl. Tackling issues such as platform independant code and well defined Object Oriented code and coding styles all in Perl.
It's an excellent addition to your Perl library. Covering a great deal of ground on building robustness into your Perl applications, without straying from it target language and the idioms of Perl.
The name is a slight misnomer as the topic of Debugging with Perl's debugger is not the main feature here, surprisingly: what it does is teach the authors methods to reduce the occurance of bugs.
There are many books that cover coding standards and writing dependable code. Those I've seen cater for C code, but can be applied to any language if desired. This book provides good coding disciplines in Perl, that can be adopted easily by developers.
It could be argued that there is nothing new in this book that can't be found in the wealth of online documentation that the Perl community provides. Martin Brown has consolidated a wealth of Perl Documentation into one physical location, and picked a 'best path' through any disparities.
For me this book was an excellent read, filling gaps and introducing new uses for familiar concepts. It falls down as a "Real Perl Book" in as much that it is muted in it's references to the Perl Community and the wealth of libraries, reading material and tutorials it provides for free.