Right away, this album has a problem, just because of its title. We can sit and argue about what constitutes a "Top 100 TV Theme," but clearly some of these do not belong: For example, "Merrie Melodies" and "Looney Tunes" weren't TV themes at all; they were music from theatrically released cartoons. Yes, you heard them on television on local kiddie shows, but they weren't designed for a television program, so technically they aren't really TV themes.
We have to get nit-picky here because all true collectors of this type of material are! And if you have previously purchased the series of "Television's Greatest Hits" discs from TVT, you already have the bulk of what's on this 2 CD set. Many of the tracks were lifted directly from those earlier discs, like "Mary Tyler Moore," which added the MTM cat meow to the end of the theme on that earlier disc and kept it here (also note that the MTM theme is still the "how will you make it on your own" version from season one of the series and not the "who can turn the world on with her smile" recording most people remember). Also from those previous discs, "The Jetsons," and "The Addams Family" which combines the Opening and Closing themes of their shows appear again here. And some of these tracks are actually only the closing themes to the programs, like "The Dick Van Dyke Show," "The Honeymooners," "My Three Sons," and "I Love Lucy" among several others. I understand why this happened: announcers talking over the music make it impossible to provide the actual main theme track, but there should be an asterisk next to these selections.
I hate to say it, but there are a couple of "reformulated" tracks on this disc as well, so you are not getting 100 tracks that are the originals as heard on the programs. The "Cagney & Lacey" theme and "Newlywed Game" and "Dating Game" aren't the original tracks that most collectors have been seeking for ages. And what did they do to the "Dynasty" theme?! Also the "Love, American Style" theme is incorrectly credited to The Cowsills here, when it was "The Charles Fox Singers" that performed the version on this album. Nit-picky, I know, I know!
But not to be too critical here: on the good side there are some great original themes that weren't included previously, most notably Dave Grusin's fantastic "St. Elsewhere" track which was incorrectly left off of the previous "Television's Greatest Hits" series.
In conclusion, if you are blessed to be a normal, average person not obsessed about such things as which season's theme you are listening to, and you don't already have the other TVT material, you will definitely get some pleasure from this 2 disc set.