If you have ever had the slightest curiosity about Nietzsche this would make an excellent starting point. Hollingdale makes a selection from his own superb translations that, as he explains in his introduction, have been ordered for maximum benefit of the reader. What you will make of this is anybody's guess. Some perhaps will run to the hills and avoid any book with Nietzsche's name on it forever but others will have the pleasure of looking further and further into the works of one of the most fascinating people that ever lived.
This is a far easier approach to Nietzsche than trying to read, say, Thus Spake Zarathustra. As good (and essential)as TSZ is it's unlikely to give a great deal of insight into its author if read without the backstory. But whatever happens do read Hollingdale's excellent introduction, in the final two and a half pages he succeeds in giving an overview of Nietzsche that seems to have eluded many an academic.